In the negative mode mass spectrometry data, four compounds related to the polymerization of cyanoacrylate were identified, and their structures were determined from accurate mass and MS/MS. A mechanism is proposed for the formation of these compounds that are regarded as intermediates in the polymerization reaction. In addition, based on the fuming of standard endogenous compounds, this study suggests that fatty acids and amino acids are the major catalytic nucleophiles that initiate the polymerization reactions. (publisher abstract modified)
Downloads
Similar Publications
- Physical and Biochemical Factors Affecting the Recovery and Analysis of DNA from Human Skeletal Remains
- Detection of Synthetic Cathinones in Seized Drugs Using Surface-enhanced Raman Spectroscopy (SERS)
- Dyed Hair and Swimming Pools: The Influence of Chlorinated and Nonchlorinated Agitated Water on Surface-Enhanced Raman Spectroscopic Analysis of Artificial Dyes on Hair